مهندسی مکانیک مدرس

مهندسی مکانیک مدرس

Experimental Assessment of Fracture in Rigid Nanocomposite Foams Weakened by a Pre-Crack in Mixed-Mode I/II

نوع مقاله : مقاله پژوهشی

نویسندگان
1 Department of Mechanical Engineering, Yazd University, Yazd, Iran.
2 Department of Mechanical Engineering, Yazd University, Yazd, Iran
10.48311/mme.2025.96909.0
چکیده
Rigid nanocomposite foams reinforced with nanoclay have low density and high mechanical strength. Additionally, they offer improved thermal and fracture properties, making them attractive for advanced structural applications. This study, examines the effect of nanoclay content (0, 1, 2, and 3 wt%) on the mechanical and fracture behavior of rigid Polyurethane (PUR) foams under mixed-mode I/II loading. The samples are produced using ultrasonic dispersion and subjected to uniaxial tensile and fracture experiments with Asymmetric Edge Notch Disc Bend (AENDB) specimens. Fracture toughness and stress intensity factors are analyzed using Finite Element Modeling (FEM). The results show that adding up to 2 wt% of nanoclay enhances tensile and fracture resistance, while 3 wt% reduces strength due to nanoparticle agglomeration. Significantly, the specimen with 2 wt% of nanoclay shows the best performance, with about 35% increase in tensile strength, 25% in fracture displacement, and up to 32% improvement in fracture load under Mixed-Mode I/II conditions. In contrast, the 3 wt% sample exhibits reductions of about 18% in tensile properties and 16% in mixed-mode fracture load. These findings highlight the importance of optimizing nanoclay concentration to achieve superior fracture performance in rigid PUR foams
کلیدواژه‌ها

موضوعات


عنوان مقاله English

Experimental Assessment of Fracture in Rigid Nanocomposite Foams Weakened by a Pre-Crack in Mixed-Mode I/II

نویسندگان English

Mohammad Mahdi Touiserkani 1
Mahdi Heydari Meybodi 2
1 Department of Mechanical Engineering, Yazd University, Yazd, Iran
2 Department of Mechanical Engineering, Yazd University, Yazd, Iran
چکیده English

Rigid nanocomposite foams reinforced with nanoclay have low density and high mechanical strength. Additionally, they offer improved thermal and fracture properties, making them attractive for advanced structural applications. This study, examines the effect of nanoclay content (0, 1, 2, and 3 wt%) on the mechanical and fracture behavior of rigid Polyurethane (PUR) foams under mixed-mode I/II loading. The samples are produced using ultrasonic dispersion and subjected to uniaxial tensile and fracture experiments with Asymmetric Edge Notch Disc Bend (AENDB) specimens. Fracture toughness and stress intensity factors are analyzed using Finite Element Modeling (FEM). The results show that adding up to 2 wt% of nanoclay enhances tensile and fracture resistance, while 3 wt% reduces strength due to nanoparticle agglomeration. Significantly, the specimen with 2 wt% of nanoclay shows the best performance, with about 35% increase in tensile strength, 25% in fracture displacement, and up to 32% improvement in fracture load under Mixed-Mode I/II conditions. In contrast, the 3 wt% sample exhibits reductions of about 18% in tensile properties and 16% in mixed-mode fracture load. These findings highlight the importance of optimizing nanoclay concentration to achieve superior fracture performance in rigid PUR foams

کلیدواژه‌ها English

Nanocomposite
Nanoclay
PUR Foam
Mixed-Mode I/II Fracture
Finite Element Modeling
[1] S. S. Ray and M. Okamoto, "Polymer/layered silicate nanocomposites: a review from preparation to processing," Progress in polymer science, vol. 28, no. 11, pp. 1539-1641, 2003.DOI: 10.1016/j.progpolymsci.2003.08.002.
[2] G. Harikrishnan, T. U. Patro, and D. Khakhar, "Polyurethane foam− clay nanocomposites: nanoclays as cell openers," Industrial & Engineering Chemistry Research, vol. 45, no. 21, pp. 7126-7134, 2006. DOI: 10.1021/ie0600994.
[3]   P. Saraeian, H. Tavakoli, and A. Ghassemi, "Production of polystyrene-nanoclay nanocomposite foam and effect of nanoclay particles on foam cell size," Journal of Composite Materials, vol. 47, no. 18, pp. 2211-2217, 2013. DOI 10.1177/0021998312454906.
[4]   B. Saboori and M. R. Ayatollahi, "CNT influence on fracture toughness of a polymer-based nanocomposite under the out-of-plane shear in comparison with pure tensile loading conditions," (in eng), Modares Mechanical Engineering, vol. 16, no. 10, pp. 441-447, 2017. [Online]. Available: http://mme.modares.ac.ir/article-15-5980-en.html.
[5]   M. Kamali Moghaddam and M. Tahani, "Study the effect of environment temperature on mechanical and fracture behavior of carbon nanotubes," (in eng), Modares Mechanical Engineering, vol. 17, no. 3, pp. 87-92, 2017. [Online]. Available: http://mme.modares.ac.ir/article-15-8685-en.html.
[6]   C. Zeng, N. Hossieny, C. Zhang, B. Wang, and S. M. Walsh, "Morphology and tensile properties of PMMA carbon nanotubes nanocomposites and nanocomposites foams," Composites science and technology, vol. 82, pp. 29-37, 2013. DOI: 10.1016/j.compscitech.2013.03.024.
[7]   M. Colloca, N. Gupta, and M. Porfiri, "Tensile properties of carbon nanofiber reinforced multiscale syntactic foams," Composites Part B: Engineering, vol. 44, no. 1, pp. 584-591, 2013. DOI: 10.1016/j.compositesb.2012.02.030.
[8]   M. Santiago-Calvo, J. Tirado-Mediavilla, J. L. Ruiz-Herrero, M. Á. Rodríguez-Pérez, and F. Villafane, "The effects of functional nanofillers on the reaction kinetics, microstructure, thermal and mechanical properties of water blown rigid polyurethane foams," Polymer, vol. 150, pp. 138-149, 2018. DOI: 10.1016/j.polymer.2018.07.029.
[9]   K. Cherednichenko, D. Kopitsyn, E. Smirnov, N. Nikolaev, and R. Fakhrullin, "Fireproof nanocomposite polyurethane foams: a review," Polymers, vol. 15, no. 10, p. 2314, 2023. DOI: 10.3390/polym15102314.
[10] R. Babaei, M. M. Touiserkani, M. Khanchoupan, and A. Afradi, "Numerical Simulation of the Effect of Conventional and Hybrid Nanofluids on the Cooling Performance of Automobile Radiator," Journal of Science and Technology in Mechanical Engineering, vol. 3, no. 2, pp. 137-151, 2025. DOI: 10.22034/STME.2025.504084.1103.
[11] H. Movahhedi Aleni, G. H. Lighat, M. h. Pol, and A. Afrouzian, "An experimental investigation on mode-II interlaminar fracture toughness of nanosilica modified glass/epoxy fiber-reinforced laminates," (in eng), Modares Mechanical Engineering, vol. 15, no. 3, pp. 283-290, 2015. [Online]. Available: http://mme.modares.ac.ir/article-15-4924-en.html.
[12] M. Heydari-Meybodi, S. Saber-Samandari, and M. Sadighi, "A new approach for prediction of elastic modulus of polymer/nanoclay composites by considering interfacial debonding: experimental and numerical investigations," Composites Science and Technology, vol. 117, pp. 379-385, 2015. DOI: 10.1016/j.compscitech.2015.07.014.
[13] m. Kerman Saravi, M. H. Pol, and M. H. Sattari, "Experimental investigation of the influence of adding nanotubes on Mode I interlaminar fracture toughness of laminated composites," (in eng), Modares Mechanical Engineering, vol. 16, no. 3, pp. 193-201, 2016. [Online]. Available: http://mme.modares.ac.ir/article-15-9931-en.html.
[14] F. Guo, S. Aryana, Y. Han, and Y. Jiao, "A review of the synthesis and applications of polymer–nanoclay composites," Applied Sciences, vol. 8, no. 9, p. 1696, 2018. DOI: 10.3390/app8091696.
[15] A. Ghasemi and M. Gharehbash, "Ductile Fracture Analysis of Notched Epoxy Nanocomposites Reinforced with Graphene Oxide Nanoparticles Using the Equivalent Material Concept," (in eng), Modares Mechanical Engineering, vol. 24, no. 4, pp. 215-223, 2024. DOI: 10.48311/mme.24.4.215.
[16] X. Cao, L. J. Lee, T. Widya, and C. Macosko, "Polyurethane/clay nanocomposites foams: processing, structure and properties," Polymer, vol. 46, no. 3, pp. 775-783, 2005. DOI 10.1016/j.polymer.2004.11.028.
[17] M. Saha, M. E. Kabir, and S. Jeelani, "Enhancement in thermal and mechanical properties of polyurethane foam infused with nanoparticles," Material Science and Engineering: A, vol. 479, no. 1-2, pp. 213-222, 2008. DOI :10.1016/j.msea.2007.06.060.
[18] E. S. Ali and S. Ahmad, "Bionanocomposite hybrid polyurethane foam reinforced with empty fruit bunch and nanoclay," Composites Part B: Engineering, vol. 43, no. 7, pp. 2813-2816, 2012. DOI: 10.1016/j.compositesb.2012.04.043.
[19] A. Kausar, I. Rafique, and B. Muhammad, "Aerospace application of polymer nanocomposite with carbon nanotube, graphite, graphene oxide, and nanoclay," Polymer-Plastics Technology and Engineering, vol. 56, no. 13, pp. 1438-1456, 2017. DOI: 10.1080/03602559.2016.1276594.
[20] N. V. Gama, A. Ferreira, and A. Barros-Timmons, "Polyurethane foams: Past, present, and future," Materials, vol. 11, no. 10, p. 1841, 2018. DOI: 10.3390/ma11101841.
[21] H. Somarathna, S. Raman, D. Mohotti, A. Mutalib, and K. Badri, "The use of polyurethane for structural and infrastructural engineering applications: A state-of-the-art review," Construction and Building Materials, vol. 190, pp. 995-1014, 2018. DOI: 10.1016/j.conbuildmat.2018.09.166.
[22] M. M. Touiserkani and M. Heydari Meybodi, "On the use of J-integral criterion for fracture assessment of cracked rigid polyurethane foam loaded in mixed mode I/II and I/III," Journal of Solid and Fluid Mechanics, vol. 14, no. 3, pp. 141-151, 2024. DOI: 10.22044/jsfm.2024.14305.3847.
[23] R. H. Alasfar, S. Ahzi, N. Barth, V. Kochkodan, M. Khraisheh, and M. Koç, "A review on the modeling of the elastic modulus and yield stress of polymers and polymer nanocomposites: Effect of temperature, loading rate and porosity," Polymers, vol. 14, no. 3, p. 360, 2022. DOI: 10.3390/polym14030360.
[24] R. K. Ramakrishnan and N. S. Sumitha, "Nanoclay-reinforced polymers," in Nanoclay-based sustainable materials: Elsevier, 2024, pp. 91-114. DOI: 10.1016/B978-0-443-13390-9.00006-0.
[25] I. Javni, W. Zhang, V. Karajkov, Z. Petrovic, and V. Divjakovic, "Effect of nano-and micro-silica fillers on polyurethane foam properties," Journal of Cellular Plastics, vol. 38, no. 3, pp. 229-239, 2002. DOI: 10.1177/0021955X02038003139.
[26] Z. Sajadian, S. M. Zebarjad, and M. Bonyani, "Thermal and mechanical properties of honeycomb sandwich panel of polyurethane nanocomposite reinforced with nanoclay," Journal of Polymer Research, vol. 31, no. 9, p. 284, 2024. DOI: 10.1007/s10965-024-04130-0.
[27] S. Chuayjuljit, A. Maungchareon, and O. Saravari, "Preparation and properties of palm oil-based rigid polyurethane nanocomposite foams," Journal of Reinforced Plastics and Composites, vol. 29, no. 2, pp. 218-225, 2010. DOI: 10.1177/0731684408096949.
[28] S. Kim, M. Lee, H. Kim, H. Park, H. Jeong, K. Yoon, and B. Kim, "Nanoclay reinforced rigid polyurethane foams," Journal of Applied Polymer Science, vol. 117, no. 4, pp. 1992-1997, 2010. DOI: 10.1002/app.32116.
[29] R. R. Maharsia and H. D. Jerro, "Enhancing tensile strength and toughness in syntactic foams through nanoclay reinforcement," Material Science and Engineering: A, vol. 454, pp. 416-422, 2007. DOI: 10.1016/j.msea.2006.11.121.
[30] Q. Zhang, X. Lin, W. Chen, H. Zhang, and D. Han, "Modification of rigid polyurethane foams with the addition of nano-SiO2 or lignocellulosic biomass," Polymers, vol. 12, no. 1, p. 107, 2020. DOI: 10.3390/polym12010107.
[31] H. Zarei, M. Fallah, H. Bisadi, A. Daneshmehr, and G. Minak, "Multiple impact response of temperature-dependent carbon nanotube-reinforced composite (CNTRC) plates with general boundary conditions," Composites Part B: Engineering, vol. 113, pp. 206-217, 2017. DOI: 10.1016/j.compositesb.2017.01.021.
[32] M. H. Meybodi, S. Saber-Samandari, M. Sadighi, and M. R. Bagheri, "Low-velocity impact response of a nanocomposite beam using an analytical model," Latin American Journal of Solids and Structures, vol. 12, no. 2, pp. 333-354, 2015. DOI: 10.1590/1679-78251346.
[33] M. M. Touiserkani and M. Heydari-Meybodi, "Out-of-plane fracture in plane strain conditions: A novel criterion with analytical and experimental evaluation in thick PUR foam," Mechanics of Materials, p. 105499, 2025. DOI: 10.1016/j.mechmat.2025.105499.
[34] S. Yao, Z. Chen, P. Xu, Z. Li, and Z. Zhao, "Experimental and numerical study on the energy absorption of polyurethane foam-filled metal/composite hybrid structures," Metals, vol. 11, no. 1, p. 118, 2021. DOI: 10.3390/met11010118.