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Research Subject: Removal of industrial wastewater especially from textile and dyeing factories is always important actions to control of pollutions. Using of polymeric adsorbents is an important method for removal of dyes from industrial wastewater. In this research work, designing and fabrication of PVA-based adsorbent with proper potential for removal of green malachite from industrial wastewater has been reported.
Research Approach: For fabrication of adsorbent 4 wt.% PVA was gelled in the present of 10 wt.% glutaraldehyde as cross-linker and punched. The punched hydrogels were porous with freeze drying method. For improving the adsorption ability, graphene and TiO₂ were used. The adsorption of green malachite with prepare adsorbent was measured timely to determine the optimum percentage of nanoparticles. In addition, the effect of contact time and the presence of UV on the adsorption of pollution was investigated. Finally, the adsorption isotherms and thermodynamics study were investigated in different time.
Main Results: The results of adsorption of pollution with PVA/graphene adsorbent in different times showed that 0.5 wt.% is the optimum loading of graphene in the PVA matrix. This value was 3 wt.% for TiO₂. The adsorption percentage via optimum adsorbent in dark condition showed that one minute after addition of adsorbent the adsorption percent increased to 75% indicating the high capability of the adsorbent in adsorption of tested pollution. The porous structure was confirmed via SEM image. By comparing the correlation coefficient for Langmuir and Freundlich isotherms it was found that Freundlich isotherm has better agreement with the findings of the current study. In other words, adsorption of green malachite with fabricated adsorbent was done multi layered. The thermodynamics studies showed that due to negative value of Gibbs energy the adsorption reaction of green malachite with fabricated absorbent is automatically.

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Research Subject: In this paper, the adsorbents used to remove lead ion using adsorption operation have been reviewed.
Research Approach: The types of adsorbents used to remove lead ions, the modifications of adsorbents, adsorption conditions, isotherms and adsorption capacity of adsorbents have been investigated and compared based on the literature survey.
Main Results: Modification by impregnation of functional groups has a significant role in increasing the adsorption capacity. The pH of the solution plays an important role in the adsorption of lead ions and generally the adsorption capacity increases by increasing the pH of the solution. Langmuir's isotherm model has been more consistent with the equilibrium data. Among the reviewed adsorbents, carbon-based adsorbents such as activated carbon and graphen-oxide, modified by chemicals such as ammonium persulfate or polyamines, show higher adsorption. Also, biomasses due to their abundance and low prices have the potential to be used as lead ion adsorbents.

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Research subject: In recent years, due to limited water resources and the extraordinary increase in nitrates in the environment, efforts to remove and control in order to benefit from the natural adsorbents have been made. Although according to the negatively charged surface of bentonite particles, absorbent needs improvement.
Research approach: In the current study, the adsorption of nitrate columns by the modified calcium montmorillonite adsorbent was investigated. Furthermore, In order to change the surface load and increase the adsorption efficiency, three-step acid leaching, oxidation layering, and loading of the cationic surfactant hexadecyltrimethylammonium bromide on the adsorbent were performed. Molecular interaction and crystallography of pure montmorillonite and synthetic nano-adsorbent (ACZ) were characterized by Fourier transform infrared spectroscopy and X-ray analysis. Moreover, the morphology of ACZ nano adsorbents was evaluated using Transmission electron microscopy and scanning electron microscopy.
Main results: Nanoparticle compaction and less access to pores and cavities in the fixed bed column reduced the adsorbent capacity inside the column compared to the discontinuous system.
The results showed that an increase in inlet concentration from 80 to 150 mg/L increased the adsorption capacity from 67.39 to 88.25 mg/g. Reducing the inlet flow rate increased the penetration time, interaction, and greater access to the binding sites for nitrate ions and finally improved the column performance and increased the inlet flow rate reduced the adsorption capacity and breakthrough time. Therefore, the adsorption of nitrate ions by the stage of internal mass transfer is controlled and depends on the duration of interaction and the possibility of penetration into the active sites. With increasing the bed height from 4.2 to 9 cm, there was a significant increase in adsorption capacity from 60.608 to 77.167 mg/g. The effect of detergents and recovery showed an absorption column; After 3 leaching steps, acid leaching played an important role in increasing column recovery. Experimental data with correlation coefficients of R²>0.95 corresponded to Thomas and Yoon-Nelson kinetic models.
In this study, the ACZ nano adsorbent column for rapid removal of nitrate ions from aqueous solutions was introduced and for use in reusable systems was proposed.
 

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Research subject: Activated carbon is a porous absorbent with reasonable specific surface area, pore volume, and pore size distribution for many applications such as adsorption. This material is obtained from various natural sources of carbon. Due to increasing demand for activated carbon, the economical precursors have been highly noticed. In the meanwhile, black liquor, industrial residue from Lignin Kraft process in paper factories, has high amount of carbon which can be used as an appropriate and cheap precursor for activated carbon production, and make high value added.
Research approach: In this study, at first, lignin was extracted from black liquor, prepared from Iran wood & paper industries-Chouka factory, under defined conditions and investigation of pH effect, and then, powdered carbon was synthesized from extracted lignin using chemical activation method by phosphoric acid chemical agent. To consider the effects of activation temperature parameter on activated carbon structure, including specific surface area, pore volume, and pore size distribution, three activation temperature of 400, 500 and 600 ^⁰C in impregnation ratio of 2 were investigated. To study the physical and morphological properties of sensitized absorbents, they were analyzed by BET, SEM, and FTIR methods.
Main results: The results confirmed that the highest amount of lignin with a similar structure to the degraded lignin was recovered at pH = 2. Investigation of the effect of activation temperature parameter suggested that the activation temperature of 500 ^°C can be a reasonable temperature for the synthesis of high specific surface area activated carbon and increasing the temperature above 500 ^°C is not effective. Among these sensitized adsorbents, the activated carbon sensitized in activation temperature of 500 ^⁰C showed the highest specific surface area and the pore volume of 1573.31 m²/g and 0.89 cm³/g respectively, which exhibits the high potential of this precursor as activated carbon adsorbent.

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Contamination of water and soil with heavy metals poses serious risks and threats to human health and the environment, and therefore finding an effective solution to remove these metals is very necessary. In this research, magnetic nanoparticles MnFe₂O₄ @ SiO₂ functionalized with N-phosphonomethyl aminodiacetic acid with core-shell structure were synthesized. These nanoparticles were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, (TGA) thermal gravimetric analysis, transmission electron microscope (TEM), and (VSM) vibration sample magnetometer. The performance of this synthetic nanoadsorbent for removing Cr (VI), Cu (II) ions from aqueous solutions was evaluated by various parameters such as adsorbent amount, contact time effect on adsorption rate and pH effect. The results show that the adsorption efficiency increases with raising pH (2.5-5) and the best adsorbent performance in the adsorption process of Cr ((VI) and Cu (II) ions at pH 7 was observed. The amount of R in the Freundlich adsorption diagram of copper ion is higher than the Langmuir isotherm. As a result, the adsorption of copper ions on the adsorbent follows the Freundlich adsorption equation. In addition, the amount of R in the Freundlich adsorption diagram for chromium ion is higher than the Langmuir isotherm. Therefore, the absorption of chromium ions on the adsorbent follows the Freundlich adsorption equation. In conclusion, a high n value indicates a favorable and effective absorption in the Freundlich equation. The adsorption data were analyzed by the Langmuir and Freundlich isotherm model. In addition, the recyclability and reuse of the adsorbent was investigated. The results show that no significant reduction in adsorbent activity is observed.
 

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Most of dyes used in production processes caused serious environmental pollution when discharged to the water resources. Azo dyes are the most used synthetic compounds in the industries such as textile, food, leather and cosmetic. Due to their toxicity and hard degradation, these kinds of compounds are classi fied as environmental hazardous materials that have to be treated before discharging to the environment. Direct blue 71 (DB 71) is one of azo dyes that is resistant to aerobic degradation and under anaerobic condition is reduced to potential carcinogenic aromatics. Different kinds of physical, chemical and biological methods such as adsorption, ultra filtration, reverse osmosis, coagulation and electro coagulation are widely used for efficient dye removal but they just transport contaminants from water to sludge and generate secondary wastes which need more treatment. Adsorption with many advantages is a proper method that is applied to treat dye compounds. In recent years, use of low cost materials as adsorbent for dye removal has been highlighted. Since natural absorbents are inexpensive and may be achieved without any cost and they are usually in abundance in nature, absorption of solute ions by these materials are a proper method to eliminate color from polluted waters and industrial wastewaters. In this study, removal of azo dye Direct Blue 71 was evaluated with two new natural adsorbents of walnut and peanuts shells. These adsorbents are produced from agricultural wastes. The effect of pH, contact time and adsorbent dosage on the removal efficiency has been studied. According to the results, maximum removal of dyes by the two natural absorbents (0.75 gr/L walnut shell in 50 mg/L initial dye concentration with pH of 9 in 45 minutes and 1 gr/L peanut shell in 50 mg/L initial dye concentration with pH of 9 in 60 minutes) was 55 and 60 percent, respectively. Comparison of prepared adsorbent in the laboratory and commercial ones in optimum condition have similar dye removal efficiency that means suitable and cheap adsorbent could be prepared in the laboratory. Removal efficiency of DB71 was also obtained 85 and 83 by the two walnut and peanut shells adsorbent powder, respectively. The results have also shown that amongst four isotherms of Langmuir, Freundlich, Temkin and Dubinin-radushkevich, Freundlich isotherm has the highest correlation coefficient which implying heterogeneous surface of adsorbent for both sorbents. It has also shown that the maximum surface adsorbent capacity for the monolayer of activated carbon of the walnut and peanut shells were 26 and 28 mg/gr, respectively. From the n values 3.58 and 3.72 of the Freundlich isotherm for both adsorbent of walnut and peanut shells, it could be concluded that physical adsorption process has been happened. The data could also indicate that pseudosecond- order was the best adsorption kinetics model for the two adsorbents

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In the present study, for the first time, adsorbent bed of SWS-1L/water adsorption chiller with rectangular and trapezoidal finned flat-tube heat exchanger with has been simulated three dimensionally based on the distributed parameters model and finite volume method. Effects of some important parameters on the chiller performance such as bed averaged pressure, temperature and uptake variations with cycle time have been examined for better understanding of bed dynamic behavior. Also, a comparative study between two different configurations of adsorbent bed including rectangular and trapezoidal fins has been conducted based on identical adsorbent mass. For this purpose, bed temperature, uptake and pressure distributions as well as the vapor flow patterns at the end of heating cycle phases and also effects of fin height and spacing on the system performance have been studied. In this investigation at fixed bed length of 20mm, fin height and spacing variations have been examined in the range of 8-20mm and 3-12mm, respectively. Results indicated that the system performance with rectangular and trapezoidal adsorbent beds are almost similar except for those conditions which fin spacing is 3mm and fin height are 14, 20mm. For the mentioned dimensions, the specific cooling power (SCP) of rectangular beds are almost 5% and 17% (for fin heights of 14 and 20mm, respectively) better than those of trapezoidal beds. Maximum and minimum SCP of adsorption chiller with flat-tube heat exchanger were obtained about 882 and 163W/kg for the smallest and the largest bed geometry and operating conditions considered in this study.

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In the present study, adsorbent bed of an adsorption chiller with finned flat-tube heat exchanger has been simulated three dimensionally based on the heat and mass transfer model with finite volume method. To examine the inter-particle mass transfer resistance effects on the system performance parameters, two different configurations of adsorbent bed including rectangular and trapezoidal fins with identical length and adsorbent mass have been considered and the effects of bed length on the system performance for different fin height and fin pitch have been studied. Moreover, effects of bed length for different particle diameters and also heating source temperatures have been investigated. Results indicated that increasing of bed length (or in the other words increasing of inter-particle resistance) increases and decreases cycle time and specific cooling power, respectively, yet the coefficient of performance is not influenced. Also, increasing bed length reduces the difference between specific cooling power of rectangular and trapezoidal beds if there is any. Moreover it is clear that optimum particles size increase with bed length increase. Finally, it is shown that effect of higher heating fluid temperature on specific cooling power improvement for beds with smaller length is more significant than those with longer length.

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Biochar and activated carbon, as carbon-rich porous materials, have wide environmental applications. In the present research, rice husk (RH) was used for preparation of biochar at 400, 600, and 800 °C under simple pyrolysis, physically-activated carbon with water steam, chemically-activated carbon with potassium hydroxide (KOH), and physiochemically-activated carbon with KOH and steam. Physical and chemical properties of biochar and activated carbons were characterized using nitrogen adsorption–desorption isotherm, Fourier transform, infra-red analysis, and Boehm method. The results showed that carbonization temperature and activation agents had significant effects on the characteristics of the samples. Activated carbon produced by KOH activation had the highest surface area (2201 m² g^-1) and total pore volume (0.96 cm³ g^-1). High concentration of sodium (Na) is an important limiting factor to reuse poor quality water resources in arid and semiarid regions. The sorption capacity of biochars and activated carbons was investigated by performing batch sorption experiments using Na as adsorbate. Na sorption was increased with increasing surface area and pore volume. The highest Na sorption capacity of 134.2 mg g^-1 was achieved by the KOH activated carbon, which has the highest surface area and pore volume. The kinetic data were well-fitted to pseudo-first order and intra-particle diffusion models.

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