Showing 3 results for Impregnation
Volume 4, Issue 3 (12-2020)
Abstract
Research Subject: The conversion of anthropogenous CO2 gas into value-add chemicals known as solar fuel technology attracted much consideration from the beginning of the 21st century owing to the potential of this technology in solving the climate change and energy shortage issues.
Research Approach: In the current study, Bismuth and copper modified TiO2 were prepared using sol-gel and wet impregnation method in order to investigate as a catalyst for photocatalytic conversion of carbon dioxide into renewable methane.
Main Results: The results of X-ray diffraction analysis, Field emission scanning microscope images and Transmission electron microscope images demonstrated that titanium dioxide nanoparticles with 20 nm in size were synthesized that after the addition of bismuth, the size of particles became smaller. Also, using energy dispersive x-ray analysis and elemental mapping technique, it was determined that the bismuth and copper were uniformly inserted in the prepared nanoparticles. Diffuse reflectance spectroscopy showed that the bandgap became smaller in bismuth and copper-containing samples, which resulted in visible light absorption. In addition, photoluminescence spectroscopy showed an impressive decrease in the rate of electron-hole separation in the prepared nanocomposite. The result of CO2 photoreduction experiments revealed that the incorporation of 3 wt% Bismuth and 1.5 wt% copper into the structure of TiO2 would increase the amount of methane production to 7.6 times greater than bare TiO2. This superior activity for methane generation could be related to the ability of bismuth compounds in adsorption and activation of carbon dioxide molecules and also the efficient separation of charge carriers given by copper. Additionally, the smaller particle size and increase in the surface area had also a positive effect on the CO2 reduction enhancement.
Sayed Mostafa Hosseinalipour, Mohammadmehdi Namazi, Arvin Behravan, Khashayar Ghadiri, Masoud Madadelahi,
Volume 14, Issue 9 (12-2014)
Abstract
In the present study, fabrication and performance testing of a flameless catalytic pad has been investigated. The catalyst was prepared with 1g of H2PtCl6.6H2O solved in 0.5 liter solvent contains 50% water and 50% ethanol and sprayed on the alumina - silica fiber mat as the catalyst support. The wet pad was dried and calcined before usage. The performance of the heater was evaluated by design and fabrication of a test stand which was capable of measuring parameters such as temperature at surface and in depth of the catalyst layer, the amount of pollutants such as CO and NOx, flow rate and pressure of the fuel and surface air circulation in front of the pad. In addition, by placing the panel containing the pad in an environmental test chamber, the effect of different climate conditions in five cities of Iran, i.e., Borojerd, Khalkhal, Lavan, Mahshahr and Puladshahr were investigated. Average surface temperature of the pad was measured about 350°C. No NOx was detected and CO emission of the burner was measured up to 5ppm. In Khalkhal conditions with the lowest temperature and humidity, the highest temperature at surface was recorded and the maximum CO emissions in Mahshahr with the highest temperature and humidity was about 3ppm. It was shown that increasing the fuel flow rate increases the surface temperature and CO emissions. It was also shown that an increase of environment temperature and humidity, increases the surface temperature.
Mohamad Hossein Mohammadipour, Mohammad Golzar,
Volume 17, Issue 6 (8-2017)
Abstract
This paper presents a numerical model for predicting pressure, impregnation and pulling force in pultrusion die which circular cross section witch two reinforcement fibrous tows pass through it. Pulling force and degree of impregnation are the most important parameters associated with pultrusion process that determine production cost and quality of pultruded profile respectively. Main idea in this approach is obtaining characteristic equations in purely polymer region and purely fibrous region and establishing relations between them by using conservation law. The superiority of this approach compared to other methods is ability to considering both straight and conical part of the die, calculating pulling force, ability of investigating influence of a variety of parameters such as those associated with die geometry, material rheology and process parameters. In this paper the influence of fibers position and fibers radius on pulling force, impregnation and pressure inside die is investigated. Due to the ability of simultaneous calculation of force and impregnation, this model can be used to establish an optimum condition between cost and quality of produced profiles.