Showing 3 results for Transesterification
Ali Zenouzi, Barat. Ghobadian, Teymoor Tvakoli Hashjin, Mehdi Feyzolahnejad, Hassan Bagherpour,
Volume 10, Issue 2 (9-2010)
Abstract
In this research, biodiesel was initially produced from waste vegetable oil by transesterification reaction. The main properties of this fuel were compared with the ASTM D-6751 standard.then, performance of MF-399 tractor engine was tested and evaluated by using 5 to 25 percent biodiesel and diesel blends. Test results showed that, the power and torque of MF-399 tractor engine were increased, using biodiesel and diesel blends. This is because of good combustion of biodiesel due to high oxygen content of this fuel. There was also a slight increase in the fuel consumption and specific fuel consumption of biodiesel and diesel blends due to low calorific value of biodiesel. Results show that the B5D95 blend has the best performance and the lowest increase in specific fuel consumption among the other blends. The fuel consumption and specific fuel consumption of B25D75 was lower than the B20D80 blend. Therefore, if the goal is using high amount of biodiesel, B25D75 blend is recommended for use in MF-399 tractor engine.
Volume 15, Issue 4 (7-2013)
Abstract
Biodiesel fuel, which is produced by transesterification reaction between alcohol and vegetable oil/animal fat is proposed as a clean alternative to petro diesel fuel. Today, one of the new technologies to produce biodiesel is using ultrasonic energy that makes production faster, with improved quality and less expensive. Various factors that affect the design of ultrasonic reactors are ratio of vibrating rod diameter to reactor diameter, reactor height, depth of horn penetration into fluid and chamber characteristics (material and shape). In this paper, two parameters namely the ratio of vibrating rod diameter to reactor diameter and reactor height were studied in order to increase the reaction efficiency. In all performed tests, the horn diameter of 14 mm, molar ratio of alcohol to oil of 5 to 1, catalyst concentration of 0.7% wt?? oil, depth of horn penetration into fluid of 15 mm and a cylindrical reactor were used. Experimental design involved the use of Central Composite Design (CCD) and the statistical Response Surface Methodology (RSM). Considering the empirical model, a significant relationship was found between independent and dependent variables with a regression coefficient of 0.99. Taking into account the desirability of increasing the efficiency, the optimal function of reactor diameter and reactor height were 63 and 110 mm, respectively with a reaction yield of 87%. In order to verify the model, function responses in the defined area were tested with five replicates and the average efficiency of the reaction was 87.2%. The obtained model suggests the simultaneous reverse effects of reactor diameter and height on the reaction efficiency.
Alireza Zahedi, Mohammad Mirabdoli, Ardeshir Shayan Nezhad,
Volume 16, Issue 9 (11-2016)
Abstract
In recent years, coinciding with the expansion of biofuel production, attempts have also been made to optimize production processes. In this study, Response Surface Methodology (RSM) was used to investigation the transesterification reaction of rapeseed oil for biodiesel production. Three main factors in order to convert triglycerides into fatty acid methyl esters (FAME) were applied according to a central composite design. These factors were catalyst concentration (NaOH), reaction temperature and time. The yield of methyl ester as the first response was determined using NMR method. The second response was the commercial cost of production. The results showed that the best conditions for producing biodiesel in constant the molar ratio of 1: 6 oil: methanol were the temperature of 47.27 oC, NaOH concentration of 1.24 %wt/wt and reaction time of 30 min. At these optimum conditions, the yield of methyl ester and cost of production is 77.67% and 67 ¢, respectively. Also, some chemical and physical properties of biodiesel were compared with petro-diesel fuel. According to the results, biodiesel fuel is a suitable substitute for petro-diesel fuel.