Volume 20, Issue 6 (June 2020)
Modares Mechanical Engineering 2020, 20(6): 1555-1565 |
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Kamkar S, Mohammadi M, Karimi M. Assessment of the Corrosion and Tribological Properties of Double Layer Nitride Coatings Performed by Plasma Nitriding and Cathodic Arc Evaporation on Ti-6Al-4V Alloy. Modares Mechanical Engineering 2020; 20 (6) :1555-1565
URL: http://mme.modares.ac.ir/article-15-34212-en.html
URL: http://mme.modares.ac.ir/article-15-34212-en.html
1- Chemical & Materials Engineering Faculty, Shahrood University of Technology, Shahrood, Iran
2- Chemical & Materials Engineering Faculty, Shahrood University of Technology, Shahrood, Iran ,majid.mohammadi@shahroodut.ac.ir
2- Chemical & Materials Engineering Faculty, Shahrood University of Technology, Shahrood, Iran ,
Abstract: (3631 Views)
High corrosion resistance, proper mechanical properties, and biocompatibility of Ti-6Al-4V alloy make it suitable for medical (dentistry and orthopedic implants), military and electronic industries. The greatest disadvantages of this alloy are poor wear resistance, low fatigue strength and poor tribological properties. The aim of this study was to apply an adhesive coating to improve both corrosion and wear properties of the Ti-6Al-4V alloy. Surface modification of alloy was done by nitrogen plasma nitriding in both electrolyte plasma and atmosphere plasma environment. Finally, the TiN layer was coated on the modified samples, using cathodic arc evaporation technique. The microstructural investigation, surface morphology, and coating thickness were studied by field emission scanning electron microscope (FESEM) equipped with energy dispersive spectroscopy. The grazing incidence X-ray diffraction (GIXRD) was applied to study the phases in the coatings. The corrosion resistance was studied with potentiodynamic polarization and electrochemical impedance spectroscopy. The wear resistance and the coating coefficient of friction were tested with pin-on-disc machine. The corrosion resistance of the samples was improved by applying the coatings and the plasma-nitride/TiN double-layer coating showed the best corrosion resistance with current density of 1.46×10-7A/cm2 and corrosion potential of -0.3V. On the other hand, the lowest thickness reduction in wear test was observed in double-layer coatings, so that the thickness reduction for both double-layer coatings, was less than 4μm, after 300m sliding.
Keywords: Plasma Nitriding, Cathodic Arc Evaporation, Plasma Electrolytic (PE), Titanium Nitride (TiN), Wear, Corrosion
Article Type: Original Research |
Subject:
Metal Forming
Received: 2019/06/25 | Accepted: 2019/12/2 | Published: 2020/06/20
Received: 2019/06/25 | Accepted: 2019/12/2 | Published: 2020/06/20
References
1. Shah FA, Trobos M, Thomsen P, Palmquist A. Commercially pure titanium (cp-Ti) versus titanium alloy (Ti6Al4V) materials as bone anchored implants - Is one truly better than the other?. Materials Science & Engineering C, Materials for Biological Applications. 2016;62:960-966. [Link] [DOI:10.1016/j.msec.2016.01.032]
2. Krząkała A, Służalska K, Dercz G, Maciej A, Kazek A, Szade J, et al. Characterisation of bioactive films on Ti-6Al-4V alloy. Electrochimica Acta. 2013;104:425-438. [Link] [DOI:10.1016/j.electacta.2012.12.081]
3. Damir Kakaš PT, Miletić A, Kovačević L, Vilotić M, Branko Škorić DK. Friction and wear of low temperature deposited TiN coating sliding in dry conditions at various speeds. Technical Gazette. 2013;20(1):27-33. [Link]
4. Samanta A, Bhattacharya M, Ratha I, Chakraborty H, Datta S, Ghosh J, et al. Nano- and micro-tribological behaviours of plasma nitrided Ti6Al4V alloys. Journal of the Mechanical Behavior of Biomedical Materials. 2018;77:267-294. [Link] [DOI:10.1016/j.jmbbm.2017.09.013]
5. Cui W, Qin G, Duan J, Wang H. A graded nano-TiN coating on biomedical Ti alloy: Low friction coefficient, good bonding and biocompatibility. Materials Science and Engineering: C. 2017;71:520-528. [Link] [DOI:10.1016/j.msec.2016.10.033]
6. Datta S, Das M, Balla VK, Bodhak S, Murugesan VK. Mechanical, wear, corrosion and biological properties of arc deposited titanium nitride coatings. Surface and Coatings Technology. 2018;344:214-222. [Link] [DOI:10.1016/j.surfcoat.2018.03.019]
7. Raimondi MT, Pietrabissa R. The in-vivo wear performance of prosthetic femoral heads with titanium nitride coating. Biomaterials. 2000;21:907-913. [Link] [DOI:10.1016/S0142-9612(99)00246-X]
8. R.P. van Hove, I.N. Sierevelt, B.J. van Royen, P.A. Nolte. Titanium-nitride coating of orthopaedic implants: A review of the literature. Biomed Research International. 2015;(2015):485975-485975. [Link] [DOI:10.1155/2015/485975]
9. Yerokhin AL, Nie X, Leyland A, Matthews A, Dowey SJ. Plasma electrolysis for surface engineering. Surface and Coatings Technology. 1999;122(2-3):73-93. [Link] [DOI:10.1016/S0257-8972(99)00441-7]
10. Pham VH, Jun SH, Kim HE, Koh YH. Deposition of titanium nitride (TiN) on Co-Cr and their potential application as vascular stent. Applied Surface Science. 2012;258(7):2864-2868. [Link] [DOI:10.1016/j.apsusc.2011.10.149]
11. de Souza GB, da Silva BA, Steudel G, Gonsalves SH, Foerster CE, Lepienski CM. Structural and tribo-mechanical characterization of nitrogen plasma treated titanium for bone implants. Surface and Coatings Technology. 2014;256:30-36. [Link] [DOI:10.1016/j.surfcoat.2013.12.009]
12. Belkin PN, Kusmanov SA, Zhirov AV, Belkin VS, Parfenyuk VI. Anode plasma electrolytic saturation of titanium alloys with nitrogen and oxygen. Journal of Materials Science & Technology. 2016;32(10).1027-1032. [Link] [DOI:10.1016/j.jmst.2016.06.005]
13. Zhang S, Zhu W. TiN coating of tool steels: A review. Journal of Materials Processing Technology. 1993;39(1-2):165-177. [Link] [DOI:10.1016/0924-0136(93)90016-Y]
14. Roşu RA, Şerban VA, Bucur AI, Dragoş U. Deposition of titanium nitride and hydroxyapatite-based biocompatible composite by reactive plasma spraying. Applied Surface Science. 2012;258(8):3871-3876. [Link] [DOI:10.1016/j.apsusc.2011.12.049]
15. Lv Y, Ji L, Liu X, Li H, Zhou H, Chen J. The structure and properties of CrAlN films deposited by mid-frequency unbalanced magnetron sputtering at different substrate bias duty cycles. Surface and Coatings Technology. 2012;206(19-20):3961-3969. [Link] [DOI:10.1016/j.surfcoat.2012.03.068]
16. Kusmanov SA, Smirnov AA, Silkin SA, Parfenyuk VI, Belkin PN. Plasma electrolytic nitriding of alpha- and beta-titanium alloy in ammonia-based electrolyte. Surface and Coatings Technology. 2016;307:1291-1296. [Link] [DOI:10.1016/j.surfcoat.2016.08.019]
17. Yildiz F, Yetim AF, Alsaran A, Çelik A. Plasma nitriding behavior of Ti6Al4V orthopedic alloy. Surface and Coatings Technology. 2008;202(11):2471-2476. [Link] [DOI:10.1016/j.surfcoat.2007.08.004]
18. Ghasemi S, Shanaghi A, Chu PK. Corrosion behavior of reactive sputtered Ti/TiN nanostructured coating and effects of intermediate titanium layer on self-healing properties. Surface and Coatings Technology. 2017;326(Part A):156-164. [Link] [DOI:10.1016/j.surfcoat.2017.07.046]
19. Mohammadi M, Godarzi M, Taherian R. Investigation of the electrical properties and corrosion resistance of TiN coating deposited by reactive sputtering on the titanium bipolar plate, used in polymeric fuel cell. Iranian Journal of Ceramic Science & Engineering. 2019;7(4):39-50. [Persian] [Link]
20. Zhang L, Chen Y, Feng YP, Chen S, Wan QI, Zhu JF. Electrochemical characterization of AlTiN, AlCrN and AlCrSiWN coatings. International Journal of Refractory Metals and Hard Materials. 2015;53(Part B):68-73. [Link] [DOI:10.1016/j.ijrmhm.2015.03.018]
21. Lin CS, Ke CS, Peng H. Corrosion of CrN and CrN/TiN coated heat-resistant steels in molten A356 aluminum alloy. Surface and Coatings Technology. 2001;146-147:168-174. [Link] [DOI:10.1016/S0257-8972(01)01484-0]
22. Jehn HA. Improvement of the corrosion resistance of PVD hard coating-substrate systems. Surface and Coatings Technology, 2000;125(1-3):212-217. [Link] [DOI:10.1016/S0257-8972(99)00551-4]
23. Elmkhah H, Abdollah-Zadeh A, Mahboubi F, Sabur RouhaghdamAR, Fattah-Alhosseini A. Correlation between the duty cycle and the surface characteristics for the nanostructured titanium aluminum nitride coating deposited by pulsed-DC PACVD technique. Journal of Alloys and Compounds. 2017;711:530-540. [Link] [DOI:10.1016/j.jallcom.2017.03.120]
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