Modares Mechanical Engineering

Modares Mechanical Engineering

Numerical simulation of non-premixed combustion and the effect of variations in the mass flow rate ratio of air to fuel on flame stability, combustion efficiency and pollutant indices

Document Type : Original Article

Authors
Mechanical Engineering Department, Hormozgan University, Bandar abbas, Iran
10.48311/mme.2026.119655.82988
Abstract
Optimizing the performance of non-premixed burners to simultaneously achieve high thermal efficiency, low pollutant emissions, and maintain robust operational stability requires computational fluid dynamics (CFD) predictive tools that accurately model turbulence-chemistry interactions (TCI) at the microscale. Conventional Reynolds-Averaging Navier-Stokes (RANS) models often suffer from poor capture of microscale effects for predicting thermal NOx formation and near-quenching phenomena. This study, employing a dual numerical approach, couples an adapted RANS solver with a large eddy simulation (LES) framework equipped with a flame-generated manifold model (FGM) and the GRI-Mech 3.0 kinetic mechanism, and validates both against experimental data. This combined approach is used to predict the performance of a fuel-air coflow burner under systematic variations in the air-to-fuel mass flow ratio (MFR). Time-frequency analysis of fluid and thermodynamic oscillations identified a dominant low-frequency (10–50 Hz) hydrodynamic instability related to the collapse of vortices in the flow separation zone. Quantitative results showed that while co-current airflow-maintained carbon conversion efficiency (CCE) above 80% up to MFR=5 and strongly reduced NOx emissions through thermal dilution, increasing the dilution ratio resulted in reduced thermal stability and increased risk of sustained hydrodynamic oscillations. This comparative modeling approach provides a robust predictive framework for the design of safer and more efficient industrial burners. The LES-FGM model demonstrated superior accuracy in capturing TCI, flame stability boundaries, and thermal NOx sensitivity compared to RANS, especially in high-strain regions.
Keywords
Subjects

[1] R. S. Barlow and J. H. Frank, "Piloted CH4/Air Flames C, D, E, and F–Release 2.0, 20-JAN-2003," in TNF Workshop, Sandia National Laboratories, 1998.
[2] R. Cabra, J. Y. Chen, R. W. Dibble, A. N. Karpetis, and R. S. Barlow, "Lifted methane–air jet flames in a vitiated coflow," Combustion and Flame, vol. 143, no. 4, pp. 491-506, 2005. doi: 10.1016/j.combustflame.2005.07.008.
[3] R. Cabra, T. Myhrvold, J. Y. Chen, R. W. Dibble, A. N. Karpetis, and R. S. Barlow, "Simultaneous laser Raman-Rayleigh-LIF measurements and numerical modeling results of a lifted turbulent H2/N2 jet flame in a vitiated coflow," Proceedings of the Combustion Institute, vol. 29, no. 2, pp. 1881-1888, 2002. doi: 10.1016/S1540-7489(02)80228-0.
[4] M. Matalon, "Intrinsic flame instabilities in premixed and nonpremixed combustion," Annual Review of Fluid Mechanics, vol. 39, no. 1, pp. 163-191, 2007. doi: 10.1146/annurev.fluid.38.050304.092153.
[5] J. Buckmaster, "Edge-flames and their stability," Combustion Science and Technology, vol. 115, no. 1-3, pp. 41-68, 1996. doi: 10.1080/00102209608935543.
[6] X. Zhang, S. Wang, and Y. Liu, "Heat release rate responses in self-excited thermoacoustic instabilities of tangential swirling non-premixed flames," Physics of Fluids, vol. 37, no. 3, 2025. doi: 10.1063/5.0256646.
[7] P. Palies, "Flow and flame mechanisms for swirl-stabilized combustors," Aerospace, vol. 12, no. 5, p. 430, 2025. doi: 10.3390/aerospace12050430.
[8] Y. Dagan, E. Arad, and Y. Tambour, "The evolution of local instability regions in turbulent non-premixed flames," Journal of Fluid Mechanics, vol. 803, pp. 18-50, 2016. doi: 10.1017/jfm.2016.488.
[9] D. Li and M. Ihme, "Stability diagram and blow-out mechanisms of turbulent non-premixed combustion," Proceedings of the Combustion Institute, vol. 38, no. 4, pp. 6337-6344, 2021. doi: 10.1016/j.proci.2020.06.331.
[10] M. Kazemi, S. Brennan, and V. Molkov, "Stability of non-premixed turbulent methane flames: Numerical simulations of the critical diameter and flame stability limits," Fuel Processing Technology, vol. 275, p. 108249, 2025. doi: 10.1016/j.fuproc.2024.108249.
[11] Z. Liu, Y. Tu, H. Zhang, H. Liu, Z. Luo, and S. Zhang, "Comparison of combustion, emission and flame stabilization characteristics for NH3/CH4 mixtures between premixed and non-premixed modes: A joint experimental and LES investigation," Fuel, vol. 405, p. 136797, 2026. doi: 10.1016/j.fuel.2025.136797.
[12] J. Guo, P. Liu, R. Serrano-Bayona, E. Es-sebbar, X. Gao, W. L. Roberts, and H. G. Im, "Stability and NO formation of ammonia/methane non-premixed flames under O2/CO2 environments," Combustion and Flame, vol. 283, p. 114621, 2026.doi: 10.1016/j.combustflame.2025.114621.
[13] A. Morel and T. Boushaki, "Combustion of NH3/CH4 mixtures in a swirl burner: Study of non-premixed flames with radial fuel injection," Experimental Thermal and Fluid Science, p. 111630, 2025. doi: 10.1016/j.expthermflusci.2025.111630.
[14] R. Santhosh and R. Yadav, "Flame Stabilization Modes in Non-Premixed NH3/H2/N2 swirling flames-A numerical study," Combustion Science and Technology, pp. 1-23, 2025. doi: 10.1080/00102202.2025.2509855.
[15] M. Biebl, J. Leicher, A. Giese, and C. Wieland, "A comprehensive study of non-premixed combustion of ammonia and its blends: Flame stability and emission reduction," Fuel, vol. 386, p. 134501, 2025. doi: 10.1016/j.fuel.2024.134501.
[16] Y. M. Al-Abdeli and A. R. Masri, "Stability characteristics and flowfields of turbulent non-premixed swirling flames," Combustion Theory and Modelling, vol. 7, no. 4, p. 731, 2003. doi: 10.1088/1364-7830/7/4/005
[17] M. Safavi and E. Amani, "A comparative study of turbulence models for non-premixed swirl-stabilized flames," Journal of Turbulence, vol. 19, no. 11-12, pp. 1017-1050, 2018. doi: 10.1080/14685248.2018.1527033
[18] A. Asadifard, S. Tabe-Jamaat, A. Zandilak, and B. Karimi, "Measurement and Analysis of Combustion Performance Parameters by Adding a Chamber to a Two-Spiral Burner," Fuel and Combustion, vol. 18, no. 4, pp. 50-80, 2026. doi: 10.22034/jfnc.2026.564242.1452.
[19] F.-c. Zhao, B.-g. Sun, S. Yuan, L.-z. Bao, H. Wei, and Q.-h. Luo, "Experimental and modeling investigations to improve the performance of the near-zero NOx emissions direct-injection hydrogen engine by injection optimization," International Journal of Hydrogen Energy, vol. 49, pp. 713-724, 2024. doi: 10.1016/j.ijhydene.2023.09.289.
[20] A. Ahsan, H. Ahsan, J. S. Olfert, and L. W. Kostiuk, "Quantifying the carbon conversion efficiency and emission indices of a lab-scale natural gas flare with internal coflows of air or steam," Experimental Thermal and Fluid Science, vol. 103, pp. 133-142, 2019. doi: 10.1016/j.expthermflusci.2019.01.018.
[21] H. Pitsch, "Large-eddy simulation of turbulent combustion," Annual Review of Fluid Mechanics, vol. 38, no. 1, pp. 453-482, 2006. doi: 10.1146/annurev.fluid.38.050304.092133.
[22] T. Poinsot and D. Veynante, Theoretical and Numerical Combustion, 2nd ed. Philadelphia, PA: RT Edwards, Inc., 2005.
[23] H. Liu, Z. Yin, J. Le, and H. Liu, "On the subgrid dissipation concept for large eddy simulation of turbulent combustion," Combustion and Flame, vol. 258, p. 113099, 2023. doi: 10.1016/j.combustflame.2023.113099.
[24] J.-P. Legier, T. Poinsot, and D. Veynante, "Dynamically thickened flame LES model for premixed and non-premixed turbulent combustion," in Proceedings of the Summer Program, vol. 12, Stanford, CA: Center for Turbulence Research, 2000, pp. 157-168.
[25] T. Zhou and F. Li, "Large eddy simulation of non-premixed flame behavior and NOx emission characteristics in a staged combustor with multi-swirling flows," Applied Thermal Engineering, vol. 246, p. 123020, 2024. doi: 10.1016/j.applthermaleng.2024.123020.
[26] B. Cuenot, "The flamelet model for non-premixed combustion," in Turbulent Combustion Modeling: Advances, New Trends and Perspectives, Dordrecht: Springer Netherlands, 2011, pp. 43-61.
[27] S. Zadsirjan, S. Tabejamaat, E. Abtahizadeh, and J. van Oijen, "Large eddy simulation of turbulent diffusion jet flames based on novel modifications of flamelet generated manifolds," Combustion and Flame, vol. 216, pp. 398-411, 2020. doi: 10.1016/j.combustflame.2020.03.007.
[28] C. D. Pierce and P. Moin, "Progress-variable approach for large-eddy simulation of non-premixed turbulent combustion," Journal of Fluid Mechanics, vol. 504, pp. 73-97, 2004. doi: 10.1017/S0022112004008213.
[29] P. P. Singh and R. N. Roy, "Evaluation of flow and flame characteristics of turbulent bluff-body CH4-H2 flame using LES-FPV approach," Journal of Turbulence, vol. 25, no. 4-6, pp. 2352490, 2024. doi: 10.1080/14685248.2024.2352490.
[30] A. Toloui and A. Ghareghani, "Investigation of the Effect of Dimensionless Parameters on the Combustion of Carbon-Free Ammonia/Methane Fuel Mixture in Porous Environment," Fuel and Combustion, vol. 18, no. 1, pp. 1-28, 2025. doi: 10.22034/jfnc.2025.499984.1421.
[31] J. He, R. Yi, C.-p. Chen, and L. Wang, "Progress variable based filtered turbulent flame model and its application to a swirl-stabilised flame," Combustion Theory and Modelling, vol. 29, no. 6, pp. 675-694, 2025. doi: 10.1080/13647830.2024.2427670.
[32] N. Peters and F. A. Williams, "Coherent structures in turbulent combustion," in The Role of Coherent Structures in Modelling Turbulence and Mixing, Berlin, Heidelberg: Springer, 2005, pp. 364-393. doi: 10.1007/BFb0028247.
[33] A. Giusti, H. Zhang, A.-M. Kypraiou, P. M. Allison, and E. Mastorakos, "Numerical investigation of the response of turbulent swirl non-premixed flames to air flow oscillations," International Journal of Spray and Combustion Dynamics, vol. 14, no. 3-4, pp. 229-237, 2022. doi: 10.1177/17568277221114944.
[34] L. Gaipl, T. Jaravel, Q. Douasbin, and T. Poinsot, "LES of the combustion efficiency of wake stabilized methane jet flames in crossflow," Combustion and Flame, vol. 273, p. 113916, 2025. doi: 10.1016/j.combustflame.2024.113916.
[35] Z. Zhang, C. Ji, D. Pan, C. Zong, J. Bao, B. Deng, and T. Zhu, "Large eddy simulation combined with system identification method to analyze non-premixed flame transfer function," Combustion Science and Technology, vol. 197, no. 10, pp. 2433-2458, 2025. doi: 10. 1080/00102202.2024.2320675.
[36] N. Papafilippou, F. Pignatelli, A. A. Subash, M. A. Chishty, and R. Gebart, "LES of biomass syngas combustion in a swirl stabilised burner: model validation and predictions," Flow, Turbulence and Combustion, vol. 113, no. 4, pp. 1189-1214, 2024. doi: 10.1007/s10494-024-00558-y.
[37] S. Marragou, "Flow structure, mixing, flame stabilization and pollutant emissions from a coaxial dual swirl CH4/H2/air injector," Ph.D. dissertation, Institut National Polytechnique de Toulouse, 2023.  
[38] Y. Xia, A. S. Morgans, W. P. Jones, J. Rogerson, G. Bulat, and X. Han, "Predicting thermoacoustic instability in an industrial gas turbine combustor: combining a low order network model with flame LES," in ASME Turbo Expo 2017, 2017. doi: 10. 1115/GT2017-63247.
[39] D. Fredrich, W. P. Jones, and A. J. Marquis, "A combined oscillation cycle involving self-excited thermo-acoustic and hydrodynamic instability mechanisms," Physics of Fluids, vol. 33, no. 8, p. 084102, 2021. doi: 10. 1063/5.0057521.
[40] K. Wu, Y. Zhang, B. Pang, J. Liu, L. Yang, and J. Li, "Dual-mode coupling of hydrodynamic and thermoacoustic instabilities in a self-excited diffusion flame array," Proceedings of the Combustion Institute, vol. 42, p. 106034, 2026. doi: 10.1016/j.proci.2024.106034.
[41] Ahsan, Hamza. "Experimental Study on the Carbon Conversion Efficiency and Emission Indices of a Lab-Scale Air-Assisted Flare." 2019