Modares Mechanical Engineering

Modares Mechanical Engineering

Optimization Challenges in Manufacturing SiC-Al2O3-YSZ Composite Green Parts via Ceramic-Feedstock Warm Pressing Process

Document Type : Original Article

Authors
Faculty of Mechanical and Energy Engineering, Shahid Beheshti University, Tehran, Iran
10.48311/mme.2026.119836.82997
Abstract
This research presents an investigation into the optimization of ceramic-feedstock warm-pressing for the fabrication of SiC-based composites. The process integrates uniaxial warm-pressing with injection molding, employing SiC, Al2O3, YSZ, and a polymer binder. Critical challenges encountered during green body production were meticulously identified, leading to the proposal of effective solutions. Significant process advancements involved designing a mold with guide screws, implementing a dual-stage coating technique, and utilizing a pulverizer for feedstock powder preparation. Through Design of Experiments (DOE), the optimal warm-pressing parameters were determined, revealing that temperature is the primary factor controlling the binder’s rheological behavior and facilitating particle rearrangement. Hardness test data indicated that the optimal conditions for warm-pressing were 120°C, 185 bar, and 27 minutes. Microstructural examination corroborated the uniform distribution of reinforcements and the cohesive strength imparted by the binder. Furthermore, particle size analysis (distribution range: 1.37 μm; distribution slope: 3.96) indicates the suitability of this powder for the molding process.
Keywords
Subjects

[1] M. Moghadasi, W. Du, M. Li, Z. Pei, and C. Ma, "Ceramic binder jetting additive manufacturing: Effects of particle size on feedstock powder and final part properties," Ceramics International, vol. 46, no. 10, pp. 16966–16972, 2020, doi: 10.1016/j.ceramint.2020.03.280.
[2] H. Esmaeili, H. Adibi, and S. M. Rezaei, "Experimental study on grinding forces and specific energy in three different environments of grinding carbon fiber reinforced silicon carbide composite," Modares Mechanical Engineering, vol. 18, No. 01, pp. 379-387, 2018. (in Persian)
[3] T. Liu, L. Yang, Z. Chen, M. Yang, and L. Lu, "Effects of SiC content on the microstructure and mechanical performance of stereolithography-based SiC ceramics," Journal of Materials Research and Technology, vol. 25, pp. 5184–5195, 2023, doi: 10.1016/j.jmrt.2023.06.260.
[4] Y. W. Kim, and R. Malik, "SiC ceramics, structure, processing and properties,” in Encyclopedia of Materials: Technical Ceramics And Glasses, vol. 2, , pp. V2-150–V2-164, 2021, doi: 10.1016/B978-0-12-818542-1.00022-9.
[5] R. Singh, "Reliability and performance limitations in SiC power devices," Microelectronics Reliability, vol. 46, no. 5–6, pp. 713–730, 2006, doi: 10.1016/j.microrel.2005.10.013.
[6] R. Vaßen, A. Kaiser, J. Förster, H. P. Buchkremer, and D. Stöver, "Densification of ultrafine SiC powders," Journal of Materials Science, vol. 31, pp. 3623–3637, 1996, doi: 10.1007/BF00352770.
[7] M. Chen, H. Xiong, L. Zhang, X. Kang, Z. Li, and K. Zhou, "Complex-shaped TiC/Ti(C,N)-based cermet prepared via rheological press molding using highly-filled granular feedstock," International Journal of Refractory Metals and Hard Materials, vol. 115, pp. 106281, 2023, doi: 10.1016/j.ijrmhm.2023.106281.
[8] V. Onbattuvelli, S. Laddha, S. J. Park, J. P. de Souza, and S. V. Atre, "Powder injection molding of SiC for thermal management," Technology in Metallurgy, Materials and Mining, vol. 9, no. 2, pp. 123–131, 2012, doi: 10.4322/tmm.2012.019.
[9] U. Scheithauer, F. Kerber, A. Füssel, S. Holtzhausen, W. Beckert, E. Schwarzer, S. Weingarten, and A. Michaelis,  “Alternative process routes to manufacture porous ceramics: opportunities and challenges,” Materials, vol. 12, no. 4, pp. 663, 2019, doi: 10.3390/ma12040663.
[10] T. O. Psiarnetska, O. G. Kirkova, O. O. Leshchuk, M. B. Shtern, and V. V. Ivzhenko, "Development of ceramic items injection moulding technology using computer modeling," Powder Metallurgy and Metal Ceramics, vol. 60, no. 3–4, pp. 150–163, 2021, doi: 10.1007/s11106-021-00223-3.
[11] C. A. Costa, A. F. Michels, and M. E. Kipper, "Welding lines formation in holes obtained by low pressure injection molding of ceramic parts," Ceramica, vol. 64, no. 369, pp. 97–103, 2018, doi: 10.1590/0366-69132018643692260.
[12] Y. Shinoda, T. Nagano, and F. Wakai, "Fabrication of nanograined silicon carbide by ultrahigh-pressure hot isostatic pressing," Journal of the American Ceramic Society, vol. 82, pp. 771–773, 1999, doi: 10.1111/j.1151-2916.1999.tb01833.x.
[13] R. Yavari and H. Khorsand, "Numerical and experimental study of injection step, separation, and imbalance filling in low pressure injection molding of ceramic components," Journal of the European Ceramic Society, vol. 41, no. 14, pp. 6915–6924, 2021, doi: 10.1016/j.jeurceramsoc.2021.07.050.
[14] Z. H. Zhang, F. C. Wang, J. Luo, S. K. Lee, and L. Wang, "Microstructures and mechanical properties of spark plasma sintered Al–SiC composites containing high volume fraction of SiC," Materials Science and Engineering: A, vol. 527, no. 27–28, pp. 7235–7240, 2010, doi: 10.1016/j.msea.2010.07.043.
[15] M. AbdolAlizade, and H. Parva, "Design and fabrication of a 3D printer based on the selective laser sintering (SLS) technology", Modares Mechanical Engineering, vol.22, no. 10, pp.219-226, 2022.
[16] N. H. Loh and R. M. German, "Statistical analysis of shrinkage variation for powder injection molding," Journal of Materials Processing Technology, vol. 59, no. 3, pp. 278–284, 1996.
[17] C. H. K. S. Lee, "Liquid-phase sintering of SiC with Al₂O₃ additives," Journal of the American Ceramic Society, vol. 78, no. 9, pp. 2471–2477, 1995.
[18] H. M. Kim and Y. W. Kim, "Low temperature pressureless sintering of silicon carbide ceramics with alumina–yttria–magnesia–calcia," Journal of the Ceramic Society of Japan, vol. 127, no. 4, pp. 207–214, 2019, doi: 10.2109/jcersj2.19024.
[19] P. Zhao, Q. Li, R. Yi, Z. Wang, L. Lu, X. Cheng, and S. Dong, "Fabrication and microstructure of liquid sintered porous SiC ceramics through spark plasma sintering," Journal of Alloys and Compounds, vol. 748, pp. 36–43, 2018, doi: 10.1016/j.jallcom.2018.03.122.
[20] G. Magnani, A. Brentari, E. Burresi, and G. Raiteri, "Pressureless sintered silicon carbide with enhanced mechanical properties obtained by the two-step sintering method," Ceramics International, vol. 40, no. 1, pp. 1759–1763, 2014, doi: 10.1016/j.ceramint.2013.07.075.
[21] P. Dvorak, T. Barriere, and J. C. Gelin, "Direct observation of mould cavity filling in ceramic injection moulding," Journal of the European Ceramic Society, vol. 28, pp. 1923–1929, 2008, doi: 10.1016/j.jeurceramsoc.2008.02.001.
[22] Z. Zhang, Y. Zhang, H. Gong, X. Guo, Y. Zhang, X. Wang, and J. Yu, "Influence of carbon content on ceramic injection molding of reaction-bonded silicon carbide," International Journal of Applied Ceramic Technology, vol. 13, no. 5, pp. 838–843, 2016, doi: 10.1111/ijac.12570.
[23] J. H. Eom, Y. W. Kim, and C. B. Park, "Effect of forming methods on porosity and compressive strength of polysiloxane-derived porous silicon carbide ceramics," Journal of the Ceramic Society of Japan, vol. 120, no. 1401, pp. 199–203, 2012, doi: 10.2109/jcersj2.120.199.
[24] J. H. Eom, Y. K. Seo, and Y. W. Kim, "Mechanical and thermal properties of pressureless sintered silicon carbide ceramics with alumina–yttria–calcia," Journal of the American Ceramic Society, vol. 99, no. 5, pp. 1735–1741, 2016, doi: 10.1111/jace.14114.
[25] W. K. You, J. P. Choi, S. M. Yoon, and J. S. Lee, "Low temperature powder injection molding of iron micro–nano powder mixture," Powder Technology, vol. 228, pp. 199–205, 2012, doi: 10.1016/j.powtec.2012.05.016.
[26] H. Khorsand, A. A. Yousefi, and H. Abdous, "Injection molding of powder–polymer mixture: advanced method for production of complex and precise engineering parts," Basparesh, vol. 3, no. 2, pp. 4–20, 2013, doi: 10.22063/basparesh.2013.975. (In Persian)
[27] J. Jaafar, J. P. Siregar, C. Tezara, M. H. M. Hamdan, and T. Rihayat, "A review of important considerations in the compression molding process of short natural fiber composites," The International Journal of Advanced Manufacturing Technology, vol. 105, no. 7–8, pp. 3437–3450, 2019, doi: 10.1007/s00170-019-04466-8.
[28] A. R. Studart, U. T. Gonzenbach, E. Tervoort, and L. J. Gauckler, "Processing routes to macroporous ceramics: a review," Journal of the American Ceramic Society, vol. 89, no. 6, pp. 1771–1789, 2006, doi: 10.1111/j.1551-2916.2006.01044.x.
[29] G. Wen, P. Cao, B. Gabbitas, D. Zhang, and N. Edmonds, "Development and design of binder systems for titanium metal injection molding: an overview," Metallurgical and Materials Transactions A, vol. 44, no. 3, pp. 1530–1547, 2013, doi: 10.1007/s11661-012-1485-x.
[30] F. Mohd Foudzi, N. Muhamad, A. B. Sulong, and H. Zakaria, "Yttria stabilized zirconia formed by micro ceramic injection molding: rheological properties and debinding effects on the sintered part," Ceramics International, vol. 39, no. 3, pp. 2665–2674, 2013, doi: 10.1016/j.ceramint.2012.09.033.
[31] H. Soleymani, A. Fereidoon, A. Albooyeh, and M. R. Nakhaei, "Optimization of mechanical and morphological properties of polypropylene reinforced with natural rubber–perlite nanoparticles using response surface method," International Journal of Metallurgical and Materials Engineering, vol. 34, no. 2, pp. 2023–2024, 2023, doi: 10.22067/jmme.2023.80165.1092.
[32] V. Momeni, A. Askari, M. H. Allaei, and H. Zangi, "Investigating the effect of stearic acid on the mechanical, rheological, and microstructural properties of AISI 4605 feedstock for metal injection molding process," Transactions of the Indian Institute of Metals, vol. 74, no. 9, pp. 2161–2170, 2021, doi: 10.1007/s12666-021-02282-x.
[33] J. Radulovic "Powder injection moulding technology: properties, possibilities and starting activities," Scientific and Technical Review, vol. 65, no. 2, pp. 20–28, 2015, doi: 10.5937/STR1502020R.
[34] M.R. Ismael, F. Clemens, T. Graule, and M.J. Hoffmann, "Effects of different thermoplastic binders on the processability of feedstocks for ceramic co-extrusion process," Ceramics International, vol. 37, no. 8, pp. 3173–3182, 2011, doi: 10.1016/j.ceramint.2011.05.084.
[35] D. Dai, Y. Zhao, C. Cao, R. Dong, H. Zhang, Q. Liu, Z. Song, X. Zhang, Z. Zheng, and C. Zhao,  "Experimental investigation on process parameters during laser-assisted turning of SiC ceramics based on orthogonal method and response surface methodology," Materials, vol. 15, no. 14, pp. 4889, 2022, doi: 10.3390/ma15144889.
[36] D.N. Sri, R. Kottapalli, A. Pavani, C. Ganteda, E. Gouthami, A. Abd-Elmonem, S.A. Haroun, S.M. Hussain, M. Bayram, and A.H. Almaliki, "Comparison between response surface methodology and Taguchi method for dyeing process parameters optimization in fabric manufacturing by empirical planning," Scientific Reports, vol. 15, no. 1, pp. 94919, 2025, doi: 10.1038/s41598-025-94919-w.
[37] ASTM International. Standard test method for water absorption, bulk density, apparent porosity, and apparent specific gravity of fired whiteware products: ASTM C373. West Conshohocken (PA): ASTM International; 2020.
[38] H. Abdoos, H. Khorsand, and A.A. Yousefi," Torque rheometry and rheological analysis of powder–polymer mixture for aluminum powder injection molding", Iranian Polymer Journal, vol. 23, no. 10, pp. 745–755, 2014, doi: 10.1007/s13726-014-0268-1.
[39] M.E. Sotomayor, A. Várez, and B. Levenfeld, " Influence of powder particle size distribution on rheological properties of 316L powder injection moulding feedstocks", Powder Technology, vol. 200, no. 1-2, pp. 30–36, 2010, doi: 10.1016/j.powtec.2010.02.003.